Issue 109, 2016, Issue in Progress
From the journal:

RSC Advances

Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins†

Qianhui Wu,a   Fanding Zhou,a   Xiao Shu,a   Lei Jian,a   Bin Xu,b   Xueli Zheng,*a   Maolin Yuan,a   Haiyan Fu,a   Ruixiang Lia  and  Hua Chen*a  

* Corresponding authors

a Key Lab of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China
E-mail: scuhchen@163.com, zhengxueli@scu.edu.cn

b Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Zigong 643000, China

Abstract

Two new phosphorus ligands (L1 and L2) were developed for rhodium-catalyzed hydroformylation of cycloolefins. L1 produced high conversion for cyclohexene (94.7%) and high dialdehyde selectivity for NBD (97.1%) and DCPD (98.4%). Analogue pincer ligands L3–L6 with different steric and electronic character were also investigated in these hydroformylations.

Graphical abstract: Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins

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Article information

DOI
https://doi.org/10.1039/C6RA24144A
Article type
Communication
Submitted
28 Sep 2016
Accepted
29 Oct 2016
First published
31 Oct 2016

RSC Adv., 2016,6, 107305-107309

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Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins

Q. Wu, F. Zhou, X. Shu, L. Jian, B. Xu, X. Zheng, M. Yuan, H. Fu, R. Li and H. Chen, RSC Adv., 2016, 6, 107305 DOI: 10.1039/C6RA24144A

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