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Issue 109, 2016, Issue in Progress
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Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins

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Abstract

Two new phosphorus ligands (L1 and L2) were developed for rhodium-catalyzed hydroformylation of cycloolefins. L1 produced high conversion for cyclohexene (94.7%) and high dialdehyde selectivity for NBD (97.1%) and DCPD (98.4%). Analogue pincer ligands L3–L6 with different steric and electronic character were also investigated in these hydroformylations.

Graphical abstract: Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins

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Supplementary files

Article information


Submitted
28 Sep 2016
Accepted
29 Oct 2016
First published
31 Oct 2016

RSC Adv., 2016,6, 107305-107309
Article type
Communication

Synthesis and application of PNP pincer ligands in rhodium-catalyzed hydroformylation of cycloolefins

Q. Wu, F. Zhou, X. Shu, L. Jian, B. Xu, X. Zheng, M. Yuan, H. Fu, R. Li and H. Chen, RSC Adv., 2016, 6, 107305
DOI: 10.1039/C6RA24144A

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