Issue 113, 2016, Issue in Progress

Solvent free oxidative coupling polymerization of 3-hexylthiophene (3HT) in the presence of FeCl3 particles

Abstract

A solvent free oxidative coupling reaction of 3-hexylthiophene (3HT) within a nanocavity is reported. It is found that 3HT can be encapsulated in nanocavities larger than 1 nm, which corresponds to the size of the molecule. In this case, the side reaction at the 4-position in 3HT is regulated.

Graphical abstract: Solvent free oxidative coupling polymerization of 3-hexylthiophene (3HT) in the presence of FeCl3 particles

Supplementary files

Article information

Article type
Communication
Submitted
17 Sep 2016
Accepted
16 Nov 2016
First published
21 Nov 2016

RSC Adv., 2016,6, 111993-111996

Solvent free oxidative coupling polymerization of 3-hexylthiophene (3HT) in the presence of FeCl3 particles

T. Hirai, Y. Nagae, K. L. White, K. Kamitani, M. Kido, T. Uchiyama, M. Nishibori, Y. Konishi, K. Yokomachi, R. Sugimoto, K. Saigo, T. Ohishi, Y. Higaki, K. Kojio and A. Takahara, RSC Adv., 2016, 6, 111993 DOI: 10.1039/C6RA23178K

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