Issue 98, 2016, Issue in Progress
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RSC Advances

A unusual two-dimensional azido-Cu(ii) network with benzoate derivative as a co-ligand exhibiting ferromagnetic order and slow magnetic relaxation†

Xiangyu Liu,*a   Peipei Cen,ab   Feifei Li,a   Xiaohui Ma,a   Huiliang Zhou,a   Xiaoyan Chen,a   Weiming Song,a   Gang Xieb  and  Sanping Chen*b  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
E-mail: xiangyuliu432@126.com

b Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, China
E-mail: sanpingchen@126.com

Abstract

A 2D layer-like azido-copper system was constructed from linear tetranuclear metal motif with mixed-ligand bridges of carboxylate, azido and hydroxyl groups. The strong ferromagnetic coupling between Cu(II) ions was due to the counter complementarity of the multiple super-exchange pathways, leading to a dramatic magnetic order and slow relaxation.

Graphical abstract: A unusual two-dimensional azido-Cu(ii) network with benzoate derivative as a co-ligand exhibiting ferromagnetic order and slow magnetic relaxation

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Article information

DOI
https://doi.org/10.1039/C6RA20830D
Article type
Communication
Submitted
18 Aug 2016
Accepted
27 Sep 2016
First published
27 Sep 2016

RSC Adv., 2016,6, 96103-96108

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A unusual two-dimensional azido-Cu(II) network with benzoate derivative as a co-ligand exhibiting ferromagnetic order and slow magnetic relaxation

X. Liu, P. Cen, F. Li, X. Ma, H. Zhou, X. Chen, W. Song, G. Xie and S. Chen, RSC Adv., 2016, 6, 96103 DOI: 10.1039/C6RA20830D

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