Issue 107, 2016, Issue in Progress
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RSC Advances

Interaction of organodialkoxysilanolates with carbon dioxide†

M. N. Temnikov,*a   N. V. Cherkun,a   K. L. Boldyrev,ab   S. N. Zimovets,a   E. G. Kononova,a   I. V. Elmanovich,ac   M. O. Gallyamovac  and  A. M. Muzafarov*ab  

* Corresponding authors

a A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, 119991, GSP-1, Moscow, Russia
E-mail: temnikov88@ineos.ac.ru, aziz@ineos.ac.ru

b N. S. Enikolopov Institute of Synthetic Polymeric Materials, A Foundation of the Russian Academy of Sciences, Russia

c Faculty of Physics, Lomonosov Moscow State University, 119991 Leninskie gory 1-2, Moscow, Russian Federation

Abstract

A series of organo(alkoxy)disiloxanes was obtained by the reaction of carbon dioxide with sodium alkoxy(organo)silanolates under high pressure as well as by bubbling CO2 through the reaction mixture. It has been suggested that the reaction involves the intermediate formation of carbonate derivatives of sodium alkoxy(organo)silanolates.

Graphical abstract: Interaction of organodialkoxysilanolates with carbon dioxide

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Article information

DOI
https://doi.org/10.1039/C6RA19758B
Article type
Communication
Submitted
04 Aug 2016
Accepted
26 Oct 2016
First published
26 Oct 2016

RSC Adv., 2016,6, 105161-105165

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Interaction of organodialkoxysilanolates with carbon dioxide

M. N. Temnikov, N. V. Cherkun, K. L. Boldyrev, S. N. Zimovets, E. G. Kononova, I. V. Elmanovich, M. O. Gallyamov and A. M. Muzafarov, RSC Adv., 2016, 6, 105161 DOI: 10.1039/C6RA19758B

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