Issue 92, 2016, Issue in Progress
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RSC Advances

tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group†

Xiaofei Qian,a   Jianwei Han*ab  and  Limin Wang*a  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, P. R. China
E-mail: wanglimin@ecust.edu.cn, jianweihan@sioc.ac.cn

b Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, 345 Ling Ling Road, Shanghai 200237, P. R. China

Abstract

Cascades of cyclic sulfonyimines mediated by tBuOK with diaryliodonium salts has been developed, giving the diaryl ethers in good yields. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group can be obtained easily in comparision with metal-catalyzed protocols.

Graphical abstract: tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group

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Article information

DOI
https://doi.org/10.1039/C6RA19313G
Article type
Communication
Submitted
30 Jul 2016
Accepted
13 Sep 2016
First published
13 Sep 2016

RSC Adv., 2016,6, 89234-89237

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tert-Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: synthesis of diaryl ether derivatives bearing a 2-aldehyde group

X. Qian, J. Han and L. Wang, RSC Adv., 2016, 6, 89234 DOI: 10.1039/C6RA19313G

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