Issue 79, 2016, Issue in Progress
From the journal:

RSC Advances

Mn(iii)-mediated regioselective synthesis of (E)-vinyl sulfones from sodium sulfinates and nitro-olefins†

Gang Nie,a   Xiaocong Deng,a   Xue Lei,a   Qinquan Hua  and  Yunfeng Chen*a  

* Corresponding authors

a School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, People's Republic of China
E-mail: yfchen@wit.edu.cn

Abstract

An efficient Mn(III)-mediated coupling reaction of sodium sulfinates with nitro-olefins has been developed, this reaction proceeds in mild and open-flask conditions to afford (E)-vinyl sulfones with high regioselectivities and in good to excellent yields. The control experiments revealed that this transformation could involve a radical process.

Graphical abstract: Mn(iii)-mediated regioselective synthesis of (E)-vinyl sulfones from sodium sulfinates and nitro-olefins

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Article information

DOI
https://doi.org/10.1039/C6RA17842A
Article type
Communication
Submitted
13 Jul 2016
Accepted
05 Aug 2016
First published
05 Aug 2016

RSC Adv., 2016,6, 75277-75281

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Mn(III)-mediated regioselective synthesis of (E)-vinyl sulfones from sodium sulfinates and nitro-olefins

G. Nie, X. Deng, X. Lei, Q. Hu and Y. Chen, RSC Adv., 2016, 6, 75277 DOI: 10.1039/C6RA17842A

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