Issue 85, 2016
From the journal:

RSC Advances

New one-pot method for the synthesis of pyrrolidinofullerenes†

A. R. Tuktarov,*a   Z. R. Shakirova,a   Yu. G. Budnikova,b   R. B. Salikhovc  and  U. M. Dzhemileva  

* Corresponding authors

a Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Russian Federation
E-mail: tuktarovar@gmail.com

b Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Russian Federation

c Bashkir State University, Russian Federation

Abstract

The reaction of fullerene C60 with isocyanoacetates and EtMgBr in the presence of stoichiometric amounts of Ti(Oi-Pr)4 was studied for the first time. Unlike esters and nitriles of carboxylic acids and isonitriles, isocyanoacetates were found to react with C60 under the developed conditions to give N-unsubstituted pyrrolidinofullerenes. The electrochemical reduction of the C60 derivatives we synthesized was found to proceed less easily than that of C60 but more easily than that of unsubstituted pyrrolidinofullerenes.

Graphical abstract: New one-pot method for the synthesis of pyrrolidinofullerenes

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Article information

DOI
https://doi.org/10.1039/C6RA15519G
Article type
Communication
Submitted
15 Jun 2016
Accepted
19 Aug 2016
First published
23 Aug 2016
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2016,6, 81847-81851

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New one-pot method for the synthesis of pyrrolidinofullerenes

A. R. Tuktarov, Z. R. Shakirova, Yu. G. Budnikova, R. B. Salikhov and U. M. Dzhemilev, RSC Adv., 2016, 6, 81847 DOI: 10.1039/C6RA15519G

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