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Issue 76, 2016, Issue in Progress
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Upcycling spent petroleum cracking catalyst: pulsed laser deposition of single-wall carbon nanotubes and silica nanowires

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Abstract

Fluid catalytic cracking (FCC), which currently accounts for half of the worldwide petroleum refining efforts, relies on catalytic, aluminosilicate zeolite particles which slowly deactivate. As of yet, this FCC catalyst residue (FC3R) has no commercial outlet, resulting in abundant amounts of landfill-destined refuse. However, this overlooked waste has the right ingredients for the synthesis of some of today's emerging nanomaterials. High-carbon FC3R, sourced from a Uruguayan refinery, was identified as faujasite particles encased in graphitic carbon shells. We show that pulsed laser ablation of raw FC3R produces simultaneous deposition of single-wall carbon nanotubes and silica nanowires through vapour/solid–liquid–solid self-assembly in distinct zones of an oven-laser apparatus. This is an extreme revalorisation and provides a new untapped resource for research and applications in C- and Si-based nanomaterials and mesoscopic physics.

Graphical abstract: Upcycling spent petroleum cracking catalyst: pulsed laser deposition of single-wall carbon nanotubes and silica nanowires

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Publication details

The article was received on 14 Jun 2016, accepted on 24 Jul 2016 and first published on 25 Jul 2016


Article type: Paper
DOI: 10.1039/C6RA15479D
Citation: RSC Adv., 2016,6, 72596-72606
  • Open access: Creative Commons BY license
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    Upcycling spent petroleum cracking catalyst: pulsed laser deposition of single-wall carbon nanotubes and silica nanowires

    N. Souza, F. Lasserre, A. Blickley, M. Zeiger, S. Suárez, M. Duarte, V. Presser and F. Mücklich, RSC Adv., 2016, 6, 72596
    DOI: 10.1039/C6RA15479D

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