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Issue 80, 2016
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Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

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Abstract

Synthesis of coordination polymers at femtolitre scales assisted by an AFM tip has become an area of increasing interest due to the astonishing range of implications that derive from it, from gaining basic knowledge of confined reactions in femtolitre droplets to the fabrication of molecular-based devices. However, this field is still in its infancy, a reason why several new basic studies that allow us control over it are highly required. Herein we report the synthesis of [Co(CH3COO)2(μ-4,4′-bpy)] in femtolitre droplets on surfaces and the results are compared with those obtained for the same reaction at different volume scales.

Graphical abstract: Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

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Publication details

The article was received on 02 Jun 2016, accepted on 29 Jul 2016 and first published on 29 Jul 2016


Article type: Paper
DOI: 10.1039/C6RA14368G
Citation: RSC Adv., 2016,6, 76666-76672
  • Open access: Creative Commons BY-NC license
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    Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

    E. Bellido, P. González-Monje, M. Guardingo, F. Novio, A. Sánchez, M. Montero, G. Molnar, A. Bousseksou and D. Ruiz-Molina, RSC Adv., 2016, 6, 76666
    DOI: 10.1039/C6RA14368G

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