Issue 80, 2016

Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

Abstract

Synthesis of coordination polymers at femtolitre scales assisted by an AFM tip has become an area of increasing interest due to the astonishing range of implications that derive from it, from gaining basic knowledge of confined reactions in femtolitre droplets to the fabrication of molecular-based devices. However, this field is still in its infancy, a reason why several new basic studies that allow us control over it are highly required. Herein we report the synthesis of [Co(CH3COO)2(μ-4,4′-bpy)] in femtolitre droplets on surfaces and the results are compared with those obtained for the same reaction at different volume scales.

Graphical abstract: Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

Supplementary files

Article information

Article type
Paper
Submitted
02 Jun 2016
Accepted
29 Jul 2016
First published
29 Jul 2016
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2016,6, 76666-76672

Nanoscale coordination polymers obtained in ultrasmall liquid droplets on solid surfaces and its comparison to different synthetic volume scales

E. Bellido, P. González-Monje, M. Guardingo, F. Novio, A. Sánchez, M. Montero, G. Molnar, A. Bousseksou and D. Ruiz-Molina, RSC Adv., 2016, 6, 76666 DOI: 10.1039/C6RA14368G

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