Issue 65, 2016, Issue in Progress
From the journal:

RSC Advances

Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen†

Sheng-Hua Zhou,abc   Jin-Hong Lin,bc   Gang Zhao,bc   Ji-Chang Xiao*bc  and  Wei-Guo Cao*ab  

* Corresponding authors

a Department of Chemistry, Shanghai University, 99 Shangda Road, Shanghai 200444, China
E-mail: wgcao@staff.shu.edu.cn

b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: jchxiao@sioc.ac.cn

c University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by a zinc/viologen system is described. Interestingly, no iodoperfluoroalkylation product was observed without the presence of radical H-donor.

Graphical abstract: Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen

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Article information

DOI
https://doi.org/10.1039/C6RA11557H
Article type
Communication
Submitted
04 May 2016
Accepted
15 Jun 2016
First published
15 Jun 2016

RSC Adv., 2016,6, 60080-60083

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Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen

S. Zhou, J. Lin, G. Zhao, J. Xiao and W. Cao, RSC Adv., 2016, 6, 60080 DOI: 10.1039/C6RA11557H

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