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Issue 58, 2016, Issue in Progress
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Tandem allylic alcohol isomerization/oxo-Michael addition reaction promoted by Re2O7

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Abstract

Re2O7 catalyzed tandem allylic alcohol isomerization/oxa-Michael addition reaction of cyclohexadienone was developed. The reaction features a regioselective and stereoselective isomerization of allylic alcohol and diastereoselective ring closure via oxa-Michael addition. This method also enabled construction of enantiopure bicyclic enones from substrates incorporated with chiral allylic alcohol via efficient chirality transfer.

Graphical abstract: Tandem allylic alcohol isomerization/oxo-Michael addition reaction promoted by Re2O7

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Publication details

The article was received on 22 Apr 2016, accepted on 23 May 2016 and first published on 25 May 2016


Article type: Communication
DOI: 10.1039/C6RA10399E
Citation: RSC Adv., 2016,6, 52583-52586
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    Tandem allylic alcohol isomerization/oxo-Michael addition reaction promoted by Re2O7

    J. Hu, D. Xu, Q. Zhang, Y. Shang, M. Shi, Y. Huangfu, L. Liu, Rong liang, Y. Lai, Y. He, J. Gao and W. Xie, RSC Adv., 2016, 6, 52583
    DOI: 10.1039/C6RA10399E

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