Issue 60, 2016, Issue in Progress
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RSC Advances

An octanuclear Mn III4Dy III4 cluster connected via two μ5-NO3− bridges with slow relaxation of magnetization†

Feng Wang,ab   Hua Pengb  and  Yu Ding*a  

* Corresponding authors

a College of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China
E-mail: dy9802@126.com

b College of Chemistry, Central China Normal University, Wuhan 430079, China

Abstract

A unique octanuclear MnIII4DyIII4 cluster was synthesized and designated as [MnIII4DyIII4(mbm)14(μ5-NO3)2(μ-NO3)2(MeOH)2](NO3)6·12H2O (1) (mbm is (1-methyl-benzoimdazol-2-yl)methanolate). The octanuclear cluster was connected by two μ5-NO3− bridges. Magnetic studies showed that 1 displays probable single molecule magnetic behavior.

Graphical abstract: An octanuclear MnIII4DyIII4 cluster connected via two μ5-NO3− bridges with slow relaxation of magnetization

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Article information

DOI
https://doi.org/10.1039/C6RA08314E
Article type
Communication
Submitted
31 Mar 2016
Accepted
31 May 2016
First published
02 Jun 2016

RSC Adv., 2016,6, 54738-54741

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An octanuclear MnIII4DyIII4 cluster connected via two μ5-NO3− bridges with slow relaxation of magnetization

F. Wang, H. Peng and Y. Ding, RSC Adv., 2016, 6, 54738 DOI: 10.1039/C6RA08314E

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