Issue 33, 2016
From the journal:

RSC Advances

Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination†

Dan Zhu,ab   Denghu Chang,ab   Shaoyan Ganab  and  Lei Shi*abc  

* Corresponding authors

a Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China
E-mail: lshi@hit.edu.cn

b Institute of Organic Chemistry, The Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China

c State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Web: http://homepage.hit.edu.cn/pages/shilei

Abstract

A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.

Graphical abstract: Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

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Article information

DOI
https://doi.org/10.1039/C6RA01799A
Article type
Communication
Submitted
21 Jan 2016
Accepted
08 Mar 2016
First published
10 Mar 2016

RSC Adv., 2016,6, 27983-27987

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Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

D. Zhu, D. Chang, S. Gan and L. Shi, RSC Adv., 2016, 6, 27983 DOI: 10.1039/C6RA01799A

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