Issue 33, 2016

Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

Abstract

A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.

Graphical abstract: Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

Supplementary files

Article information

Article type
Communication
Submitted
21 Jan 2016
Accepted
08 Mar 2016
First published
10 Mar 2016

RSC Adv., 2016,6, 27983-27987

Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

D. Zhu, D. Chang, S. Gan and L. Shi, RSC Adv., 2016, 6, 27983 DOI: 10.1039/C6RA01799A

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