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Issue 7, 2016
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An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

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Abstract

A new synthetic route to FcPH2 and FcPCl2 (Fc = ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.

Graphical abstract: An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

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Publication details

The article was received on 24 Dec 2015, accepted on 04 Jan 2016 and first published on 08 Jan 2016


Article type: Communication
DOI: 10.1039/C5RA27594F
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RSC Adv., 2016,6, 5973-5976

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    An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

    B. A. Surgenor, L. J. Taylor, A. Nordheider, A. M. Z. Slawin, K. S. Athukorala Arachchige, J. D. Woollins and P. Kilian, RSC Adv., 2016, 6, 5973
    DOI: 10.1039/C5RA27594F

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