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Issue 26, 2016
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Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

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Abstract

Two new polyhedral tolyl-containing metallasiloxanes, {(Na+)2[TolSi(O)O]6(Ni2+)4(Na+)4(OH)2[TolSi(O)O]6}*(EtOH)14(H2O)2 and {[CuSi(O)O]12(Cu2+)4(Na+)4}*(EtOH)8}, and two new large stereoregular cyclosiloxanes, cis-[TolSi(O)OSiMe3]6 and tris-cis-tris-trans-[TolSi(O)OSiMe3]12, have been synthesized and their structures have been determined by X-ray crystallography.

Graphical abstract: Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

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Publication details

The article was received on 10 Dec 2015, accepted on 17 Feb 2016 and first published on 23 Feb 2016


Article type: Paper
DOI: 10.1039/C5RA26414F
Citation: RSC Adv., 2016,6, 22052-22060

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    Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

    A. A. Anisimov, Y. N. Kononevich, P. V. Zhemchugov, S. A. Milenin, A. A. Korlyukov, U. S. Tsareva, A. S. Peregudov, P. V. Dorovatovskii, Y. A. Molodtsova, R. U. Takazova, O. I. Shchegolikhina and A. M. Muzafarov, RSC Adv., 2016, 6, 22052
    DOI: 10.1039/C5RA26414F

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