Issue 2, 2016
From the journal:

RSC Advances

Expedient Baylis–Hillman reaction protocol to functionalize cyclohexa-2,4-dienones†‡

Santhosh Kumar Chittimalla,*a   Manikandan Koodalingam,§a   Chennakesavulu Bandi,§a   Sireesha Putturua  and  Rajesh Kuppusamya  

* Corresponding authors

a Medicinal Chemistry Department, AMRI Singapore Research Centre, 61 Science Park Road, #05-01, The Galen, Science Park III, Singapore 117525, Singapore
E-mail: santhosh.chittimalla@amriglobal.com, chemcsk@gmail.com
Fax: +65-63985511

Abstract

Several masked o-benzoquinone (MOB; 6,6-dimethoxy-cyclohexa-2,4-dienone derivatives) derivatives successfully took part in the Baylis–Hillman (BH) reaction with various aldehydes and ketones to furnish the corresponding condensation products. To our knowledge, cyclohexa-2,4-dienone systems in this study are utilized for the first time in the BH reaction.

Graphical abstract: Expedient Baylis–Hillman reaction protocol to functionalize cyclohexa-2,4-dienones

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Article information

DOI
https://doi.org/10.1039/C5RA21842J
Article type
Communication
Submitted
19 Oct 2015
Accepted
30 Nov 2015
First published
24 Dec 2015

RSC Adv., 2016,6, 1460-1465

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Expedient Baylis–Hillman reaction protocol to functionalize cyclohexa-2,4-dienones

S. K. Chittimalla, M. Koodalingam, C. Bandi, S. Putturu and R. Kuppusamy, RSC Adv., 2016, 6, 1460 DOI: 10.1039/C5RA21842J

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