Issue 7, 2016
From the journal:

Inorganic Chemistry Frontiers

Ionothermal synthesis and magnetic study of a new manganese(ii) phosphite with an unprecedented Mn/P ratio†

Tan Su,ab   Hongzhu Xing,c   Yi Li, ORCID logo *a   Junbiao Wu,ad   Xiaowei Song,a   Takehito Nakano*e  and  Jihong Yua  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: yili@jlu.edu.cn

b Institute of Theoretical Chemistry, Jilin University, Changchun 130021, P. R. China

c College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

d Department of Chemistry, College of Science, Northeastern University, Shenyang, China

e Department of Physics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: nakano@nano.phys.sci.osaka-u.ac.jp

Abstract

A new layered manganese(II) phosphite, |NH4|4[Mn4(PO3H)6] (JIS-10), has been synthesised via the ionothermal method by using 1-pentyl-3-methylimidazolium bromide ([Pmim]Br) as the solvent. JIS-10 is the first manganese phosphite with a Mn/P ratio of 2/3, whose layered framework is built by the alternate connection of Mn2O9 dimers and PO3H pseudo-tetrahedra. JIS-10 represents an antiferromagnetic dimer system with S = 5/2 for each Mn2+ ion.

Graphical abstract: Ionothermal synthesis and magnetic study of a new manganese(ii) phosphite with an unprecedented Mn/P ratio

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Article information

DOI
https://doi.org/10.1039/C6QI00014B
Article type
Research Article
Submitted
18 Jan 2016
Accepted
07 Apr 2016
First published
12 Apr 2016

Inorg. Chem. Front., 2016,3, 924-927

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Ionothermal synthesis and magnetic study of a new manganese(II) phosphite with an unprecedented Mn/P ratio

T. Su, H. Xing, Y. Li, J. Wu, X. Song, T. Nakano and J. Yu, Inorg. Chem. Front., 2016, 3, 924 DOI: 10.1039/C6QI00014B

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