Clusto-supramolecular block copolymers are synthesized by using an anionic cluster [W6O19]2− as an ionic junction to link two cationic terminated polystyrene chains. These polymers exhibit versatile self-assembly behaviours not only dependent on the molecular weight but also adaptive to the concentration and temperature.
X. Cao, L. Zhang, T. Xu, S. Zhang, H. Zhang, H. Li and L. Wu, Polym. Chem., 2016, 7, 3216 DOI: 10.1039/C6PY00514D
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