Issue 21, 2016
From the journal:

Polymer Chemistry

Synthesis and characterization of supramolecular cross-linkers containing cyclodextrin dimer and trimer†

Keisuke Iijima,a   Daisuke Aoki,a   Hiromitsu Sogawa,a   Shigeo Asaia  and  Toshikazu Takata*a  

* Corresponding authors

a Department of Organic and Polymeric Materials, Tokyo Institute of Technology, H-126, 2-12-1, Ookayama, Meguro, Tokyo 152-8552, Japan
E-mail: ttakata@polymer.titech.ac.jp
Fax: (+81)3-5734-2888

Abstract

Vinylic supramolecular cross-linkers (VSCs) were prepared by mixing an α-cyclodextrin dimer or a trimer and a polyethylene glycol-type macromonomer. DOSY NMR study exhibited the size of VSC and its dependency on the concentration and the structure of the components. Polymerization of a vinyl monomer with VSC afforded rotaxane cross-linked polymers.

Graphical abstract: Synthesis and characterization of supramolecular cross-linkers containing cyclodextrin dimer and trimer

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Article information

DOI
https://doi.org/10.1039/C6PY00367B
Article type
Communication
Submitted
29 Feb 2016
Accepted
10 Apr 2016
First published
13 Apr 2016

Polym. Chem., 2016,7, 3492-3495

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Synthesis and characterization of supramolecular cross-linkers containing cyclodextrin dimer and trimer

K. Iijima, D. Aoki, H. Sogawa, S. Asai and T. Takata, Polym. Chem., 2016, 7, 3492 DOI: 10.1039/C6PY00367B

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