Issue 11, 2016
From the journal:

Polymer Chemistry

Synthesis of a disulfide-bridged bispillar[5]arene and its application in supramolecular polymers†

Cai-Li Sun,ab   Jiang-Fei Xu,a   Yu-Zhe Chen,a   Li-Ya Niu,ab   Li-Zhu Wu,a   Chen-Ho Tunga  and  Qing-Zheng Yang*ab  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: qzyang@mail.ipc.ac.cn

b Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China

Abstract

A disulfide-bridged bispillar[5]arene was synthesized via efficient oxidation of thiol-pillar[5]arene. The resulting disulfide-bridged bispillar[5]arene was successfully applied in constructing linear supramolecular polymers which were confirmed by concentration-dependent 1H NMR spectroscopy, 2D DOSY and viscosity measurements. Such supramolecular polymers manifested redox responsiveness and were fabricated into water dispersible nanospheres with high fluorescence properties.

Graphical abstract: Synthesis of a disulfide-bridged bispillar[5]arene and its application in supramolecular polymers

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Article information

DOI
https://doi.org/10.1039/C6PY00148C
Article type
Paper
Submitted
27 Jan 2016
Accepted
16 Feb 2016
First published
17 Feb 2016

Polym. Chem., 2016,7, 2057-2061

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Synthesis of a disulfide-bridged bispillar[5]arene and its application in supramolecular polymers

C. Sun, J. Xu, Y. Chen, L. Niu, L. Wu, C. Tung and Q. Yang, Polym. Chem., 2016, 7, 2057 DOI: 10.1039/C6PY00148C

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