Metallophthalocyanines as triplet sensitizers for highly efficient photon upconversion based on sensitized triplet–triplet annihilation

Abstract

Soluble palladium and platinum phthalocyanines with coumarin moieties were synthesized with Q bands in the red and near-IR regions, in which the molar extinction coefficients were up to 1.01 × 10⁵ cm⁻¹ mol⁻¹. These metallophthalocyanines were coupled with rubrene and applied in photon upconversion systems based on triplet–triplet annihilation. The highest upconversion efficiency of the palladium phthalocyanine was 5.6%, which is higher than that of the platinum phthalocyanine–rubrene system. The larger molar extinction coefficient resulted in high upconversion capability (>10⁵ cm⁻¹ mol⁻¹) and low saturation incident power (<20 mW cm⁻²).