Issue 18, 2016

Divergent copper-mediated dimerization and hydroxylation of benzamides involving C–H bond functionalization

Abstract

Convenient methods were developed for copper-mediated oxidative C–H activation of aminoquinoline benzamides. The reaction conditions can be tuned to give either hydroxylation or dimerization compounds as the major products efficiently. Preliminary mechanistic studies suggested that different coordination states of copper may lead to different reaction outcomes.

Graphical abstract: Divergent copper-mediated dimerization and hydroxylation of benzamides involving C–H bond functionalization

Supplementary files

Article information

Article type
Paper
Submitted
19 Feb 2016
Accepted
01 Apr 2016
First published
04 Apr 2016

Org. Biomol. Chem., 2016,14, 4239-4246

Author version available

Divergent copper-mediated dimerization and hydroxylation of benzamides involving C–H bond functionalization

M. Wang, Y. Hu, Z. Jiang, H. C. Shen and X. Sun, Org. Biomol. Chem., 2016, 14, 4239 DOI: 10.1039/C6OB00392C

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