Issue 8, 2016

Enhancement of N-heterocyclic carbenes on rhodium catalyzed olefination of triazoles

Abstract

A few rhodium complexes of N-heterocyclic carbenes were prepared through carbene transfer reactions and their structures were characterized by X-ray diffraction analysis. The rhodium complexes of NHCs are found to be efficient catalysts for vinylation of various triazoles via C–H activation. A number of double vinylated triazoles can be obtained in good yields.

Graphical abstract: Enhancement of N-heterocyclic carbenes on rhodium catalyzed olefination of triazoles

Supplementary files

Article information

Article type
Paper
Submitted
21 Nov 2015
Accepted
22 Jan 2016
First published
22 Jan 2016

Org. Biomol. Chem., 2016,14, 2550-2555

Enhancement of N-heterocyclic carbenes on rhodium catalyzed olefination of triazoles

S. Zhao, F. Wu, Y. Ma, W. Chen, M. Liu and H. Wu, Org. Biomol. Chem., 2016, 14, 2550 DOI: 10.1039/C5OB02397A

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