In situ optical measurement of the rapid Li intercalation and deintercalation dynamics in colloidal 2D layered TiS2 nanodiscs

Abstract

We report the in situ optical measurements of the rapid Li intercalation and deintercalation dynamics in 2-dimensional (2D) layered transition metal dichalcogenide (TMD) with a nanoscale lateral dimension using thin films fabricated with size-controlled colloidal TiS₂ nanodiscs. The films exhibiting high optical homogeneity, where the interband absorption changes near-linearly to the amount of intercalated Li, enabled facile optical probing of the intercalation dynamics overcoming the shortcomings of amperometry susceptible to complications from non-Faradaic processes. The time scale of Li intercalation and deintercalation was on the order of seconds in the nanodiscs of ∼100 nm lateral dimension, indicating sufficiently rapid dynamic control of the intercalation-induced material properties with a reduced lateral dimension. The change in the rate and reversibility of the dynamics during the multiple intercalation/deintercalation cycles was also measured, providing a unique window to observe the effect of potential structural changes on the intercalation and deintercalation dynamics in 2D layered TMD structures with a nanoscale lateral dimension.