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Issue 7, 2016
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C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

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Abstract

TaOx grafted onto Al2O3 is investigated for C–N bond cleavage of amines under H2 pressure. Heteroaromatics such as aniline are stoichiometrically denitrogenated at high temperature, while cyclohexylamine is catalytically denitrogenated. UV-visible and X-ray photoelectron spectroscopy indicate the formation of a stable Ta–N species in the former case.

Graphical abstract: C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

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Article information


Submitted
07 Apr 2016
Accepted
23 May 2016
First published
24 May 2016

New J. Chem., 2016,40, 6001-6004
Article type
Letter

C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

M. Bachrach, T. J. Marks and J. M. Notestein, New J. Chem., 2016, 40, 6001
DOI: 10.1039/C6NJ01076H

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