Issue 7, 2016

Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes

Abstract

The room temperature hydroamination of alkynes with phenylhydrazine and anilines was achieved with an anti-Bredt di(amino) carbene gold(I) chloride as precatalyst, in the presence of KBArF as chloride scavenger. These reactions were highly regioselective and excellent conversions were obtained (up to 99%) for a series of alkynes and anilines.

Graphical abstract: Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes

Supplementary files

Article information

Article type
Letter
Submitted
29 Mar 2016
Accepted
10 May 2016
First published
11 May 2016

New J. Chem., 2016,40, 5993-5996

Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes

X. Hu, D. Martin and G. Bertrand, New J. Chem., 2016, 40, 5993 DOI: 10.1039/C6NJ00980H

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