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Issue 6, 2016
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Phosphovanadomolybdic acid catalyzed desulfurization–oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant

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Abstract

In the presence of phosphovanadomolybdic acids, e.g., H6PV3Mo9O40, desulfurization–oxygenation of various kinds of structurally diverse secondary and tertiary thioamides proceeded efficiently using molecular oxygen as the terminal oxidant, affording the corresponding amides in moderate to excellent yields. In addition, 18O-labeled amides could readily be synthesized using H218O as the oxygen source.

Graphical abstract: Phosphovanadomolybdic acid catalyzed desulfurization–oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant

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Publication details

The article was received on 16 Dec 2015, accepted on 21 Mar 2016 and first published on 22 Mar 2016


Article type: Letter
DOI: 10.1039/C5NJ03579A
Citation: New J. Chem., 2016,40, 4865-4869

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    Phosphovanadomolybdic acid catalyzed desulfurization–oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant

    N. Xu, X. Jin, K. Suzuki, K. Yamaguchi and N. Mizuno, New J. Chem., 2016, 40, 4865
    DOI: 10.1039/C5NJ03579A

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