Issue 6, 2016

Effect of synergic cooperation on optical and photoelectrochemical properties of CeO2–MnO composite thin films

Abstract

CeO2–MnO composite thin films have been deposited on glass substrates, which were coated with fluorine-doped tin oxide (FTO), by aerosol-assisted chemical vapor deposition (AACVD) using a 1 : 1 mixture of the cerium complex [Ce(OCOCF3)4][(CH3)2NHCH2CH2OH]+ (1) and acetatomanganese(II). X-ray diffraction (XRD), Raman spectroscopy and profilometry were used to investigate the phase purity, stoichiometry and thickness of the films. EDX results confirmed that the Ce : Mn ratio was 1 : 9 in the deposited composite thin films. FEG-SEM analysis illustrated that the morphology of the fabricated films was influenced by the deposition temperature and hence the optoelectronic properties. UV-vis studies of a composite thin film fabricated from methanol solution at 475 °C demonstrate a direct band gap of 2.5 eV. From its current–voltage characteristics it is evident that a CeO2–MnO composite semiconductor electrode exhibits n-type behavior and the photocurrent was strongly dependent on the deposition temperature. A CeO2–MnO photoanode deposited at 475 °C for 45 min from a 0.023 M solution of (1) and acetatomanganese(II) in methanol gave a maximum photocurrent density of 265 μA cm−2 at 0.65 V vs. Ag/AgCl/3 M KCl using a 0.5 M NaOH electrolyte.

Graphical abstract: Effect of synergic cooperation on optical and photoelectrochemical properties of CeO2–MnO composite thin films

Supplementary files

Article information

Article type
Paper
Submitted
04 Dec 2015
Accepted
03 Apr 2016
First published
04 Apr 2016

New J. Chem., 2016,40, 5177-5184

Author version available

Effect of synergic cooperation on optical and photoelectrochemical properties of CeO2–MnO composite thin films

M. A. Mansoor, M. Mazhar, M. Ebadi, H. N. Ming, M. A. Mat Teridi and L. Kong Mun, New J. Chem., 2016, 40, 5177 DOI: 10.1039/C5NJ03446A

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