Jump to main content
Jump to site search

Issue 20, 2016
Previous Article Next Article

Ru(ii)/PEG-400 as a highly efficient and recyclable catalytic media for annulation and olefination reactions via C–H bond activation

Author affiliations

Abstract

In this report synthesis of isoquinolinones, isocoumarins, and N-methyl isoquinolinones and olefination of the Weinreb amides by C–H bond activation using Ru(II)/PEG-400 as green and recyclable media are documented. This developed methodology is capable of the regioselective and stereoselctive construction of new C–C, C–O and C–N bonds by the one step cleavage of C–H, N–H, O–H and N–O bonds. This method is environmentally benign due to its peculiar characteristics such as (i) high atom economy, (ii) reuse of an expensive ruthenium based homogeneous catalytic system, (iii) mild reaction conditions with a simple extraction process and, (iv) importantly, all the systems derived from this protocol being scalable up to the gram level.

Graphical abstract: Ru(ii)/PEG-400 as a highly efficient and recyclable catalytic media for annulation and olefination reactions via C–H bond activation

Back to tab navigation

Supplementary files

Article information


Submitted
10 Jun 2016
Accepted
25 Jul 2016
First published
25 Jul 2016

Green Chem., 2016,18, 5635-5642
Article type
Paper
Author version available

Ru(II)/PEG-400 as a highly efficient and recyclable catalytic media for annulation and olefination reactions via C–H bond activation

S. L. Yedage and B. M. Bhanage, Green Chem., 2016, 18, 5635
DOI: 10.1039/C6GC01581F

Social activity

Search articles by author

Spotlight

Advertisements