Synthesis of hierarchical mesoporous Prussian blue analogues in ionic liquid/water/MgCl2 and application in electrochemical reduction of CO2

Xinchen Kang; Xiaofu Sun; Qinggong Zhu; Xiaoxue Ma; Huizhen Liu; Jun Ma; Qingli Qian; Buxing Han

doi:10.1039/C5GC02848E

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Synthesis of hierarchical mesoporous Prussian blue analogues in ionic liquid/water/MgCl₂ and application in electrochemical reduction of CO₂†

Xinchen Kang,^a Xiaofu Sun,^a Qinggong Zhu,*^a Xiaoxue Ma,^a Huizhen Liu,^a Jun Ma,^a Qingli Qian^a and Buxing Han*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: qgzhu@iccas.ac.cn, hanbx@iccas.ac.cn

Abstract

The nanodomains in ionic liquid/water/MgCl₂ solution can be tuned continuously by changing the concentration of the salts, and hierarchical mesoporous Prussian blue analogues have been successfully synthesized with controlled morphology and pore properties, which have very high activity and selectivity for electrochemical reduction of CO₂ to formic acid.

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Article information

DOI: https://doi.org/10.1039/C5GC02848E
Article type: Communication
Submitted: 28 Nov 2015
Accepted: 05 Jan 2016
First published: 05 Jan 2016

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Green Chem., 2016,18, 1869-1873

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Synthesis of hierarchical mesoporous Prussian blue analogues in ionic liquid/water/MgCl₂ and application in electrochemical reduction of CO₂

X. Kang, X. Sun, Q. Zhu, X. Ma, H. Liu, J. Ma, Q. Qian and B. Han, Green Chem., 2016, 18, 1869 DOI: 10.1039/C5GC02848E

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