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Issue 3, 2016
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Stereoselective organocatalysed reactions in deep eutectic solvents: highly tunable and biorenewable reaction media for sustainable organic synthesis

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Abstract

Three distinct stereoselective reactions, catalysed by using a chiral primary amine through different activation methods, have been successfully carried out for the first time in bio-based eutectic mixtures, thereby affording functionalised molecules in very high enantioselectivity. The use of these unconventional and biorenewable reaction media also provides opportunities for facilitating the recovery and the recycling of the chiral catalyst.

Graphical abstract: Stereoselective organocatalysed reactions in deep eutectic solvents: highly tunable and biorenewable reaction media for sustainable organic synthesis

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Publication details

The article was received on 10 Aug 2015, accepted on 01 Sep 2015 and first published on 01 Sep 2015


Article type: Paper
DOI: 10.1039/C5GC01855B
Citation: Green Chem., 2016,18, 792-797

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    Stereoselective organocatalysed reactions in deep eutectic solvents: highly tunable and biorenewable reaction media for sustainable organic synthesis

    E. Massolo, S. Palmieri, M. Benaglia, V. Capriati and F. M. Perna, Green Chem., 2016, 18, 792
    DOI: 10.1039/C5GC01855B

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