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Issue 12, 2016
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Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids

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Abstract

Assembly of cucurbit[6] and a {Cd2Ge8V12O48} cluster produced two rotaxane-shaped and polyrotaxane-shaped solids by changing the ratio of starting precursors in the system. The high oxygen density of the polyoxoanion surface provides active sites to extend a single rotaxane-shaped hybrid 1 to a 1D polyrotaxane-shaped hybrid 2. This construction strategy may afford an entirely new methodology for polyoxometalate-based hybrid chemistry.

Graphical abstract: Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids

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Article information


Submitted
04 Feb 2016
Accepted
25 Feb 2016
First published
25 Feb 2016

Dalton Trans., 2016,45, 4989-4992
Article type
Communication
Author version available

Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids

M. Wei, H. Zang, E. Zhou, K. Shao, B. Song, X. Wang and Z. Su, Dalton Trans., 2016, 45, 4989
DOI: 10.1039/C6DT00496B

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