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Issue 45, 2016
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Macrocyclic {3d–4f} SMMs as building blocks for 1D-polymers: selective bridging of 4f ions by use of an O-donor ligand

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Abstract

Crystallisation of the tetranuclear 3d–4f Single-Molecule Magnet (SMM) [CuII3TbIII(LEt)(NO3)3(MeOH)]·MeOH (1) with Na2[tpa] (tpa = terephthalate and H6LEt is the [3 + 3] imine macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene and 1,2-diaminoethane) gives a structurally characterised one-dimensional cationic polymer {[CuII3TbIII(LEt)(tpa)(H2O)3](NO3)·0.5H2O·0.25MeOH}n (2). A comparative study of the static and dynamic magnetic properties of 2 and its precursor, 1, is reported.

Graphical abstract: Macrocyclic {3d–4f} SMMs as building blocks for 1D-polymers: selective bridging of 4f ions by use of an O-donor ligand

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Article information


Submitted
26 Sep 2016
Accepted
28 Oct 2016
First published
28 Oct 2016

Dalton Trans., 2016,45, 18089-18093
Article type
Communication

Macrocyclic {3d–4f} SMMs as building blocks for 1D-polymers: selective bridging of 4f ions by use of an O-donor ligand

S. Dhers, H. L. C. Feltham, M. Rouzières, R. Clérac and S. Brooker, Dalton Trans., 2016, 45, 18089
DOI: 10.1039/C6DT03734H

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