K3[Mo2(SNO5)4Cl]3[Mo2(SNO5)4]: the first example of a heterometallic extended metal atom node (HEMAN)

Brian S. Dolinar; Stosh A. Kozimor; John F. Berry

doi:10.1039/C6DT03659G

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K₃[Mo₂(SNO5)₄Cl]₃[Mo₂(SNO5)₄]: the first example of a heterometallic extended metal atom node (HEMAN)†

Brian S. Dolinar,^a Stosh A. Kozimor^b and John F. Berry*^a

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* Corresponding authors

^a Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, WI, USA
E-mail: berry@chem.wisc.edu

^b Inorganic Isotope and Actinide Chemistry Group, Los Alamos National Laboratory, Los Alamos, NM, USA

Abstract

We present the synthesis, structure, and electrochemistry of K₃[Mo₂(SNO5)₄Cl]₃[Mo₂(SNO5)₄] (1, HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo₂(SNO5)₄Cl]⁻ units and one [Mo₂(SNO5)₄] unit tethered together by K⁺ ions.

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Article information

DOI: https://doi.org/10.1039/C6DT03659G
Article type: Communication
Submitted: 20 Sep 2016
Accepted: 14 Oct 2016
First published: 14 Oct 2016

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Dalton Trans., 2016,45, 17602-17605

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K₃[Mo₂(SNO5)₄Cl]₃[Mo₂(SNO5)₄]: the first example of a heterometallic extended metal atom node (HEMAN)

B. S. Dolinar, S. A. Kozimor and J. F. Berry, Dalton Trans., 2016, 45, 17602 DOI: 10.1039/C6DT03659G

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