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Issue 44, 2016
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Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

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Abstract

A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(I) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.

Graphical abstract: Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

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Publication details

The article was received on 13 Sep 2016, accepted on 12 Oct 2016 and first published on 24 Oct 2016


Article type: Paper
DOI: 10.1039/C6DT03564G
Citation: Dalton Trans., 2016,45, 17859-17866
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    Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

    A. Beillard, X. Bantreil, T. Métro, J. Martinez and F. Lamaty, Dalton Trans., 2016, 45, 17859
    DOI: 10.1039/C6DT03564G

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