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Issue 43, 2016
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Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

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Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Graphical abstract: Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

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Article information


Submitted
01 Sep 2016
Accepted
12 Oct 2016
First published
19 Oct 2016

Dalton Trans., 2016,45, 17104-17107
Article type
Communication

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

R. Wei, R. Nakahara, J. M. Cameron, G. N. Newton, T. Shiga, H. Sagayama, R. Kumai, Y. Murakami and H. Oshio, Dalton Trans., 2016, 45, 17104
DOI: 10.1039/C6DT03416K

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