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Issue 41, 2016
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Supramolecular 3d–4f single-molecule magnet architectures

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Abstract

The nanosized self-assemblies {[{LnIII}{H2O⊂CrIII3LnIII6}]2(H2O)} (Ln = Dy, 1 and Tb, 2) based on new 3d–4f mixed-metal coordination topologies are formed via extensive intramolecular hydrogen bonding that is directed by enclosed water molecules. Compounds 1 and 2 show single-molecule magnet characteristics manifested by hysteresis loops up to 1.6 K (Ueff = 8.3 cm−1) and 1 K (Ueff = 3.4 cm−1), respectively.

Graphical abstract: Supramolecular 3d–4f single-molecule magnet architectures

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Publication details

The article was received on 30 Aug 2016, accepted on 12 Sep 2016 and first published on 12 Sep 2016


Article type: Communication
DOI: 10.1039/C6DT03392J
Citation: Dalton Trans., 2016,45, 16148-16152
  • Open access: Creative Commons BY-NC license
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    Supramolecular 3d–4f single-molecule magnet architectures

    S. Schmitz, J. van Leusen, N. V. Izarova, Y. Lan, W. Wernsdorfer, P. Kögerler and K. Yu. Monakhov, Dalton Trans., 2016, 45, 16148
    DOI: 10.1039/C6DT03392J

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