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Issue 38, 2016
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Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3−xPdx(BTC)2]n

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Abstract

Simultaneous incorporation of palladium within Pd–Pd and/or Pd–Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu2+ by Pd2+ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).

Graphical abstract: Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3−xPdx(BTC)2]n

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Publication details

The article was received on 21 Jul 2016, accepted on 22 Aug 2016 and first published on 22 Aug 2016


Article type: Communication
DOI: 10.1039/C6DT02893D
Citation: Dalton Trans., 2016,45, 14883-14887
  • Open access: Creative Commons BY license
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    Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3−xPdx(BTC)2]n

    W. Zhang, Z. Chen, M. Al-Naji, P. Guo, S. Cwik, O. Halbherr, Y. Wang, M. Muhler, N. Wilde, R. Gläser and R. A. Fischer, Dalton Trans., 2016, 45, 14883
    DOI: 10.1039/C6DT02893D

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