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Issue 38, 2016
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Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes

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Abstract

Lanthanide contraction was used for helicity fine-tuning and helix winding control of single-helical tetranuclear complexes LZn3Ln (Ln = La–Lu); heavier lanthanides formed a tighter helix with a higher M/P ratio and gave a more abundant partially-coiled structure, resulting in 14-step structural control of the helical complexes.

Graphical abstract: Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes

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Publication details

The article was received on 02 Jul 2016, accepted on 23 Aug 2016 and first published on 23 Aug 2016


Article type: Communication
DOI: 10.1039/C6DT02635D
Citation: Dalton Trans., 2016,45, 14902-14906
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    Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes

    S. Sairenji, S. Akine and T. Nabeshima, Dalton Trans., 2016, 45, 14902
    DOI: 10.1039/C6DT02635D

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