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Issue 30, 2016
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Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

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Abstract

A highly thermally stable CP/MOF, comprised of Mg2+ and H2EBTC2− with the formula of [Mg(H2EBTC)(DMF)2], emits dual band luminescence centered at 376 and 555 nm. The former is assigned to the fluorescence of H2EBTC2− and the latter with 1.63 μs decay lifetime and large Stokes shifts corresponds to the phosphorescence of H2EBTC2−. To the best of our knowledge, this is the first time the ligand-based phosphorescence in a CP/MOF without any heavy atom at room temperature has been observed.

Graphical abstract: Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

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The article was received on 14 Jun 2016, accepted on 23 Jun 2016 and first published on 28 Jun 2016


Article type: Communication
DOI: 10.1039/C6DT02359B
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Citation: Dalton Trans., 2016,45, 11935-11938
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    Simultaneous observation of ligand-based fluorescence and phosphorescence within a magnesium-based CP/MOF at room temperature

    L. Zhai, W. Zhang, J. Zuo and X. Ren, Dalton Trans., 2016, 45, 11935
    DOI: 10.1039/C6DT02359B

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