Issue 48, 2016
From the journal:

Dalton Transactions

R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate†

Masumi Itazaki,*a   Noriko Tsuchida,‡b   Yuka Shigesato,a   Keiko Takanob  and  Hiroshi Nakazawa*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan

b Department of Chemistry and Biochemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1 Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan

Abstract

R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt; R = aryl, alkyl; X = Cl, Br) were achieved for the first time to give cis-[M(X)2{P(R)(NMeCH2)2}2]. DFT calculations suggested that the exchange reaction proceeds via a phosphenium intermediate.

Graphical abstract: R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate

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Article information

DOI
https://doi.org/10.1039/C6DT02314B
Article type
Communication
Submitted
10 Jun 2016
Accepted
17 Oct 2016
First published
24 Oct 2016

Dalton Trans., 2016,45, 19216-19220

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R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate

M. Itazaki, N. Tsuchida, Y. Shigesato, K. Takano and H. Nakazawa, Dalton Trans., 2016, 45, 19216 DOI: 10.1039/C6DT02314B

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