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Issue 40, 2016
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Group 5 chemistry supported by β-diketiminate ligands

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Abstract

β-Diketiminate (BDI) ligands are widely used supporting ligands in modern organometallic chemistry and are capable of stabilizing various metal complexes in multiple oxidation states and coordination environments. This review describes recent advances in the chemistry of group 5 metals, namely vanadium, niobium and tantalum supported by the BDI ligand framework. Special emphasis is put on the reactivity of low-valent complexes, as well as low-coordinate complexes containing reactive multiply bonded groups, such as alkylidene, imido and nitrido groups.

Graphical abstract: Group 5 chemistry supported by β-diketiminate ligands

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Publication details

The article was received on 12 May 2016, accepted on 10 Jun 2016 and first published on 21 Jun 2016


Article type: Perspective
DOI: 10.1039/C6DT01770C
Dalton Trans., 2016,45, 15725-15745

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    Group 5 chemistry supported by β-diketiminate ligands

    S. Hohloch, B. M. Kriegel, R. G. Bergman and J. Arnold, Dalton Trans., 2016, 45, 15725
    DOI: 10.1039/C6DT01770C

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