Issue 22, 2016
From the journal:

Dalton Transactions

Atypical temperature-dependence of symmetry transformation observed in a uranyl phosphonate†

Tao Zheng,ab   Yang Gao,ab   Daxiang Gui,ab   Lanhua Chen,ab   Daopeng Sheng,ab   Juan Diwu,*ab   Zhifang Chai,ab   Thomas E. Albrecht-Schmittc  and  Shuao Wang*ab  

* Corresponding authors

a School for Radiological and Interdisciplinary Sciences (RAD-X), Soochow University, Jiangsu 215123, China
E-mail: diwujuan@suda.edu.cn, shuaowang@suda.edu.cn

b Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China

c Department of Chemistry and Biochemistry, Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA

Abstract

The example of phase transformation from a centrosymmetric space group at low temperature (LT) to a chiral space group at high temperature (HT) is reported, which was clearly resolved in a single-crystal-to-single-crystal manner in a 3D uranyl(VI) phosphonate compound [TMA][(UO2)2(1,3-pbpH)(1,3-pbpH2)] (1) (TMA+ = tetramethylammonium cation; 1,3-pbpH4 = 1,3-phenylenebis(phosphonic acid)).

Graphical abstract: Atypical temperature-dependence of symmetry transformation observed in a uranyl phosphonate

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Article information

DOI
https://doi.org/10.1039/C6DT01011C
Article type
Communication
Submitted
15 Mar 2016
Accepted
06 May 2016
First published
06 May 2016

Dalton Trans., 2016,45, 9031-9035

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Atypical temperature-dependence of symmetry transformation observed in a uranyl phosphonate

T. Zheng, Y. Gao, D. Gui, L. Chen, D. Sheng, J. Diwu, Z. Chai, T. E. Albrecht-Schmitt and S. Wang, Dalton Trans., 2016, 45, 9031 DOI: 10.1039/C6DT01011C

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