Issue 22, 2016
From the journal:

Dalton Transactions

A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate†

Ze-Min Zhang,ab   Karzan H. Zangana,bc   Andreas K. Kostopoulos,b   Ming-Liang Tong*a  and  Richard E. P. Winpenny*b  

* Corresponding authors

a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn
Fax: +86 20 8411-2245

b School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk

c Departent of Chemistry, College of Education, Salahaddin University-Erbil, Kurdistan Region, Iraq

Abstract

Reaction of (aminomethyl)phosphonic acid (ampH2) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd12}, which shows a large magnetocaloric effect (MCE).

Graphical abstract: A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

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Article information

DOI
https://doi.org/10.1039/C6DT00876C
Article type
Communication
Submitted
04 Mar 2016
Accepted
05 May 2016
First published
10 May 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 9041-9044

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A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

Z. Zhang, K. H. Zangana, A. K. Kostopoulos, M. Tong and R. E. P. Winpenny, Dalton Trans., 2016, 45, 9041 DOI: 10.1039/C6DT00876C

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