A high-nuclearity metal-cyanide cluster [Mo6Cu14] with photomagnetic properties

N. Bridonneau; L.-M. Chamoreau; G. Gontard; J.-L. Cantin; J. von Bardeleben; V. Marvaud

doi:10.1039/C6DT00743K

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A high-nuclearity metal-cyanide cluster [Mo₆Cu₁₄] with photomagnetic properties†

N. Bridonneau,^a L.-M. Chamoreau,^a G. Gontard,^a J.-L. Cantin,^b J. von Bardeleben^b and V. Marvaud*^a

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* Corresponding authors

^a IPCM – CNRS UMR-8232, UPMC – Univ. Paris 6, 4 place Jussieu, 75252 Paris cedex 05, France
E-mail: valerie.Marvaud@upmc.fr
Fax: +33 (0)1 44 27 38 41

^b INSP – CNRS UMR-7588, UPMC – Univ. Paris 6, 4 place Jussieu, 75252 Paris cedex 05, France

Abstract

A high-nuclearity metal-cyanide cluster [Mo₆Cu₁₄] has been prepared and its photomagnetic properties investigated. The photoswitchable magnetic phenomenon observed is thermally reversible (T ≈ 230 K). In the field of photomagnetism, [Mo₆Cu₁₄] represents a unique example of a nanocage and the highest nuclearity observed so far.

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Article information

DOI: https://doi.org/10.1039/C6DT00743K
Article type: Paper
Submitted: 24 Feb 2016
Accepted: 20 Apr 2016
First published: 27 Apr 2016

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Dalton Trans., 2016,45, 9412-9418

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A high-nuclearity metal-cyanide cluster [Mo₆Cu₁₄] with photomagnetic properties

N. Bridonneau, L.-M. Chamoreau, G. Gontard, J.-L. Cantin, J. von Bardeleben and V. Marvaud, Dalton Trans., 2016, 45, 9412 DOI: 10.1039/C6DT00743K

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