Issue 19, 2016

A practical method for the generation of organoarsenic nucleophiles towards the construction of a versatile arsenic library

Abstract

Nucleophilic arsenic reagents were prepared in situ from a nonvolatile cyclooligoarsine. As–As bond cleavage of the cyclooligoarsine readily proceeded with anion sources. Various kinds of organoarsenic compounds were easily constructed in high yields by selecting anion sources and electrophiles. In comparison with conventional methods of As–C bond formation, a wide variety of organoarsenic compounds were safely and easily synthesized by using this method.

Graphical abstract: A practical method for the generation of organoarsenic nucleophiles towards the construction of a versatile arsenic library

Supplementary files

Article information

Article type
Communication
Submitted
24 Feb 2016
Accepted
11 Mar 2016
First published
14 Mar 2016

Dalton Trans., 2016,45, 7937-7940

A practical method for the generation of organoarsenic nucleophiles towards the construction of a versatile arsenic library

S. Tanaka, H. Imoto, T. Kato and K. Naka, Dalton Trans., 2016, 45, 7937 DOI: 10.1039/C6DT00723F

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