Issue 1, 2016
From the journal:

Dalton Transactions

Crystal-to-crystal transformation from a chain compound to a layered coordination polymer†

Jinbiao Shi,ab   Yan Zhang,c   Bin Zhang*a  and  Daoben Zhua  

* Corresponding authors

a OSL, BNLMS, CMS & Institute of Chemistry, Chinese Academy of Science, Beijing 100190, P. R. China
E-mail: zhangbin@iccas.ac.cn

b Graduate School, University of Chinese Academy of Sciences, 100049, P. R. China

c Institute of Condensed Matter, School of Physics, Peking University, Beijing 100871, P. R. China

Abstract

A crystal-to-crystal transformation was observed from a green chain compound CuBr2(1,4-dioxane)2(H2O)2 (1) to a brown layered compound (CuBr2)3(1,4-dioxane)2 (2). The hydrogen bond connecting chains in 1 were replaced by a μ-Br bridge in 2 and the antiferromagnetic interaction between the metal atoms in 2 became stronger than in 1.

Graphical abstract: Crystal-to-crystal transformation from a chain compound to a layered coordination polymer

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Article information

DOI
https://doi.org/10.1039/C5DT03985A
Article type
Communication
Submitted
12 Oct 2015
Accepted
10 Nov 2015
First published
13 Nov 2015

Dalton Trans., 2016,45, 89-92

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Crystal-to-crystal transformation from a chain compound to a layered coordination polymer

J. Shi, Y. Zhang, B. Zhang and D. Zhu, Dalton Trans., 2016, 45, 89 DOI: 10.1039/C5DT03985A

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