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Issue 15, 2016
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Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins

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Abstract

Nanosized SSZ-13 has been obtained from a one-pot synthesis procedure with the addition of CTAB to the synthesis precursor solution. Nano-SSZ-13 zeolite showed high intracrystalline mesoporosity and compared to standard SSZ-13 presented a much longer lifetime and higher conversion capacity for the reaction of methanol to olefins. The improved properties were attributed to a more efficient utilization of micropores by easier diffusion of reactants and products and slower deactivation by coke. A higher C2/C3 ratio was found for nano-SSZ-13, pointing to a lower deactivation of the aromatics cycle of the hydrocarbon pool.

Graphical abstract: Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins

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Publication details

The article was received on 26 Feb 2016, accepted on 27 Apr 2016 and first published on 27 Apr 2016


Article type: Paper
DOI: 10.1039/C6CY00433D
Catal. Sci. Technol., 2016,6, 5856-5863

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    Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins

    Z. Li, M. T. Navarro, J. Martínez-Triguero, J. Yu and A. Corma, Catal. Sci. Technol., 2016, 6, 5856
    DOI: 10.1039/C6CY00433D

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