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Abstract | Cited by

This review covers free radical additions, which are initiated by the formal addition of a hydrogen atom to a C[double bond, length as m-dash]C double bond. These reactions originated in the realms of inorganic chemistry, polymer chemistry, and organic chemistry, whereby barriers between these disciplines impeded the rapid implementation of the findings.

Graphical abstract: Markovnikov free radical addition reactions, a sleeping beauty kissed to life

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