Issue 34, 2016
From the journal:

Physical Chemistry Chemical Physics

Hydrated forms of fluoroacetic acid: a rotational study†

Gang Feng,ab   Qian Gou,ab   Luca Evangelisti,b   Lorenzo Spada,b   Susana Blancoc  and  Walther Caminati*b  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China

b Dipartimento di Chimica “G. Ciamician” dell’Università, Via Selmi 2, I-40126 Bologna, Italy
E-mail: walther.caminati@unibo.it

c Departamento de Química Física y Quim. Inorg., Facultad de Ciencias, Universidad de Valladolid, Paseo Belén 7, E-47011 Valladolid, Spain

Abstract

The rotational spectra of two conformers of the 1 : 1 adduct of fluoroacetic acid with water have been assigned by pulsed jet Fourier transform microwave spectroscopy. Their shapes differ according to the trans and cis forms of the fluoroacetic acid moiety. This is in contrast to the rotational spectrum of the monomer, for which the cis form has not been observed. Details of the hydrogen bond, structure, dynamics and energetic features of the two species are given.

Graphical abstract: Hydrated forms of fluoroacetic acid: a rotational study

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Article information

DOI
https://doi.org/10.1039/C6CP04735A
Article type
Paper
Submitted
07 Jul 2016
Accepted
27 Jul 2016
First published
30 Jul 2016

Phys. Chem. Chem. Phys., 2016,18, 23651-23656

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Hydrated forms of fluoroacetic acid: a rotational study

G. Feng, Q. Gou, L. Evangelisti, L. Spada, S. Blanco and W. Caminati, Phys. Chem. Chem. Phys., 2016, 18, 23651 DOI: 10.1039/C6CP04735A

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